WEBA preliminary study was conducted on the coal desulfurization process via NaBO 2 electroreduction with pulse voltage using a borondoped diamond (BDD) thin film electrode. It has been proved that NaBO 2 was converted into NaBH 4 by 11 B NMR. The factors that influence the conversion rate of NaBO 2 into NaBH 4 and coal .
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WEBAug 15, 2020 · The effect of coal feed size on S rej was studied by using a microwave pretreatment time of 3 min and a background field strength of 2750 Gs. As Fig. 7 shows, the desulfurization rate increased monotonically with decreasing coal particle size, attaining a maximum value of 48% when the feed particle size was − mm. The reason for this .
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WEBOct 25, 2001 · Minerals' attachment to calciumbased sorbent particles during in situ desulfurization of coal gasifiion process has been investigated. Results show that iron (Fe) from coal tends to attach itself to calcium (Ca) as a result of solid–solid reactions occurring during the process, and hence, forming complex compounds, calcium .
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WEBFeb 15, 2018 · /HAcH 2 O 2 desulfurization procedure. A mixture of HAcH 2 O 2 solvent (1:1, v/v) was chosen as the desulfurization additive, with a ratio of coal sample to additive of 1:5 (g/mL). The irradiation was performed by a microwave oven (MASII) with GHz frequency, and the microwave irradiation power was set at 500 W, with .
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WEBMost of the coal, oil and natural gas produced in the world are used as fuels and a small part is used as a chemical feedstock. Undesulfurized coal and oil in the combustion process will produce a large number of sulfur oxides (SOx), serious harm to human health, and environmental damage. The unpurified natural gas containing hydrogen sulfide .
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WEBApr 23, 2023 · The transformation from pyrite to soluble FeSO 4 and Fe 2 (SO 4) 3 is the main reason for highsulfur coal desulfurization during the process of wetgrinding. Therefore, this investigation puts forward a new and friendly desulfurization method for coal desulfurization.
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WEBOct 23, 2011 · This electrochemical reductive desulfurization (ERD) method for coal water slurry (CWS), which was an offshoot of the research Novel Desulfurization Method of Sodium Borohydride Reduction for Coal Water Slurry (Shen, Y. F.; Sun, T. H.; Jia, J. P. Energy Fuels 2011, 25, 2963–2967.), utilized hodic reduction to change some .
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WEBOct 29, 2018 · With the increasing attention on SO3 emission in coalfired power plants, the removal of SO3 acid mist in a limestonegypsum wet flue gas desulfurization (WFGD) system was investigated. The generation properties of SO3 acid mist were analyzed with an experimental system, and the effects of flue gas properties and technologies for ultralow .
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WEBFeb 8, 2017 · Coal desulfurization has been regarded as an effective pretreatment for clean fuel and less environmental pollution. The microwave irradiation was used to desulfurize the Nantong coal leached with H 2 O 2 and NaOH. The results showed the desulfurization rate of the coal is very low by directly microwave irradiation, while the .
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WEBAs mentioned above, Li proposed a new desulfurization process with sodium borohydride reduction for highsulfur coals. 19 After that, we researched the use of NaBH 4 for deep desulfurization of CWS and gasoline in depth and the common influencing factors such as reductant (NaBH 4) concentration, treatment time, coal particle size, reaction ...
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WEBMay 1, 2016 · SO 2 (approximately 5 vol.%) and oxygen (2–6 vol.%) were confirmed to be exhausted in the regenerator of a pilot plant due to the unreacted oxygen remaining in the regeneration process of the hot gas desulfurization system. In this study, copper as a alytic promoter was added to SnZrbased alyst to reduce the alyst deactivation .
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WEBOct 1, 2001 · Coal desulfurization is imperative to create clean coal and reducing harmful emissions during the combustion process. However, organic sulfur in coal is more difficult to remove than inorganic sulfur. Therefore, in this paper, a method of coal sample desulfurization using citric acid with microwave assisted was proposed, and .
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WEBSep 1, 2020 · Desulfurization from coal will prevent many environmental damages, especially air pollution. Therefore, this process is essential in order to eliminate the harmful environmental effects of coal.
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WEBThis study aims to understand the roles of hydrogen and carbon monoxide during the desulfurization process in a coal gasifiion system that H2S of the syngas was removed by Fe2O3/SiO2 sorbents. The Fe2O3/SiO2 sorbents were prepared by incipient wetness impregnation. Through the breakthrough experiments and Fourier transform infrared ...
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WEBThe zinc ferrite–silicon dioxide composite powder provides reactive, durable, and regenerable reactant for dry sulfur removal sorbent. The next step of preparation of dry desulfurization sorbent is embedding composite powder into the supporting material and shaping the honeycomb structure. Table
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WEBDec 15, 2023 · Microbial coal desulfurization in an airlift bioreactor by sulfuroxidizing bacterium Thiobacillus ferrooxidans. Fuel Process Technol. (1993) Brierley ... Then the operating mechanism and particle behavior during the coal staged conversion process were comprehensively discussed. Additionally, the effects of operating and structural ...
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WEBJun 1, 2024 · Ionic liquids (ILs) were selected and applied to investigate the best coal desulfurization through orthogonal tests. FTIR, XPS, SEM and contact angle tests were used to characterize the effect on the physical and chemical structures in coal for revealing the coal desulfurization mechanism by ILsH 2 O 2 system. The orthogonal test results .
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WEBApr 11, 2021 · Flue gas desulfurization (FGD) is the removal process of sulfur dioxide (SO2) from flue gases. Sulfur dioxide in gases is produced by the combustion of fossil fuels and many industrial processes such as gasoline refining as well as cement, paper, glass, steel, iron and copper production. Flue Gas Desulfurization (FGD) System Description
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WEBAmong the desulfurization processes, the oxidative desulfurization (ODS) process is a promising method to achieve very low and nearzero sulfur content of the fuel. In this process, sulfur compounds are converted to the corresponding sulfone by a alyst and in the presence of an oxidant. ... (MgAl, CuAl, and CoAl) on the GO as supports for ...
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WEBOct 5, 2019 · The transformation from pyrite to soluble FeSO 4 and Fe 2 (SO 4) 3 is the main reason for highsulfur coal desulfurization during the process of wetgrinding. Therefore, this investigation puts ...
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WEBJun 5, 2017 · 1. Introduction. Flue gas desulfurization (FGD) is used in many coalfired power plants to primarily reduce the emission of sulfur dioxide. Among various FGD process technologies, the wet scrubber technology is the most popular.
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WEBOct 15, 2019 · The throughput of highash and highsulfur finegrain coal (0–6 mm) increases year by serious problem of direct combustion is the formation of acid rain and, the precombustion desulfurization and ash reduction can reduce environmental pollution. A combined process of dry separation and microwave .
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WEBMar 1, 2013 · Highlights A systematical study on a novel magnesiumbased WFGD process with a spray scrubber. Na 2 S 2 O 3 was found effectively to inhibit the oxidation of desulfurization byproduct. The desulfurization efficiency could reach a high level above 90%. A desulfurization process model was established by the doublefilm theory. The .
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WEBNov 1, 2018 · The wet limestonegypsum FGD process is most widely utilized owing to its high desulfurization efficiency and reliability (Srivastava and Jozewicz, 2001; Srivastava et al., 2001). In the combustion process with coal, SO 2 as acid gas is produced.
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WEBJul 11, 2022 · Due to the most recent environmental requirements, wide desulfurization has become an increasingly important way to obtain ultraclean fuels for transportation of less than 15 ppmw of sulfur, such ...
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WEBJan 1, 1983 · The nature of the desulfurization reaction of pyrite, alone and in the pres ence of coal, was studied under conditions of the Ames process [8,9]. It was shown that in this process the sulfur is extracted by conversion into soluble forms such as sulfates.
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WEBMar 1, 2024 · Coal gangue is a solid waste generated during the coal mining and washing process [28], [29], [30]. China's coal gangue reserves and annual growth have reached –5 Gt and – Gt respectively, making it the country with the largest coal gangue reserves in the world [31], [32]. If coal gangue is used as a desulfurization agent, the ...
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WEBDec 12, 2012 · The desulfurization process is important for the reduction of harmful SO x emissions; therefore, the development of a CFD model capable of predicting chemical reactions involving desulfurization is key to the optimization of reactor designs and operating conditions. To model the process, one gaseous phase and five particulate .
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WEBApr 23, 2005 · Abstract. In this paper, a twostep desulfurization process for highsulfur coal was investigated. Two Chinese coals with the addition of 10 wt % potassium hydroxide or sodium hydroxide were ...
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WEBNov 8, 2023 · article{Chen2023ComparativeIO, title={Comparative investigation on the chemical predesulfurization process of a high sulfur coal through orthogonal experiments: a case study}, author={Yumeng Chen and Lanhui Huang and Zhendong Song}, journal={International Journal of Coal Preparation and Utilization}, year={2023}, .
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